Thesis /

ROMDOC-THESIS-2010-097

Combinaţii complexe cu liganzi macrociclici şi policiclici aromatici

Rus, Adina (UPB)
2007-01-01

Abstract: The thesis had the next objectives: • the synthesis and characterization (by elemental chemical analysis, molar electric conductivity data, infrared, X-ray and NMR spectra,) of a three new macrocyclic and polycyclic aromatic ligands: bis(8,8’–hidroxyquinoline-2,2’-carboxy) – L1, 4-(3-aminoacridin-6-il-imino)pentan-2-one - L3 şi di(3’, 5’-dimetilpirazol)-9,10-dihydro-9,10-diethano-anthracen-11,12-dione – L5. • obtained and characterized (by elemental chemical analysis, molar electric conduc tivity data, magnetic susceptibility, infrared, EPR and NMR spectra, X-ray) of 35 mono- and polynuclear complex compounds of transitonal metals (Cu(II), Mn(II), Ni(II), Co(II), Cr(III), Fe(III)) and some lanthanoides (Ce(III), Eu(III), Gd(III)) with five macrocyclic and polycyclic aromatic ligands bis(8,8’–hidroxyquinoline-2,2’-carboxy) – L1, 3,6-diaminoacridine hemisulphate - L2, 4-(3-aminoacridin-6-il-imino)pentan-2-one - L3, 3,6-diaminoacridine L4 and di(3’, 5’-dimetilpirazol)-9,10-dihydro-9,10-diethano-anthracen-11,12-dione – L5. • the study of some properties and potential applications of these complex compounds: chemiluminiscence proprieties, fluorescence,biologic activity, parasitologic tests, the establish of the age of archeological object.

Keyword(s): Liganzi macrociclici -- Teză de doctorat ; Liganzi policiclici -- Teză de doctorat ; Liganzi aromatici -- Teză de doctorat ; Chimie analitică ; Chimie fizică -- Teză de doctorat
Note: Guran, Cornelia

OPAC: See record in BC-UPB Web OPAC
Full Text: see files

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